H301 + H311 + H331 Toxic if swallowed, in contact with skin or if inhaled H351 Suspected of causing cancer. %PDF-1.5 *If this is your primary analyte of interest, sample for 60 min at 0.05 L/min (3L). HWn9)tanamm}%)R;:@EHQ3julrx7?;oys_l}^G{Rx$OW|hc.3mq],}8I7 9:6QBqZr34BiC}{ . Exposure would cause irritation with only minor residual injury (e.g. First aiders need to protect themselves. Our recommendations on filtering respiratory protection are based on the following standards: DIN EN 143, DIN 14387 and other accompanying standards relating to the used respiratory protection system. These Safety Data Sheets may not be changed, or altered in any way without the expressed knowledge and permission of Methanex Corporation. Workers may be harmed by exposure to methyl alcohol. There is no need to contact SLTC before sampling. Risk of explosion. Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. Based on available data the classification criteria are not met. l.KN rBy~ahCoUT Safety Data Sheet Methanol Version 1.7 Revision Date: 10/14/2014 MSDS Number: 100000002748 1 / 20 Methanol SECTION 1. << E}4.pe8dnh]r;]@+5zVnV8&gm!b]sW{c W\,q?Pgc9iyI[(eoQ>/;zs` endstream endobj 1 0 obj <> endobj 2 0 obj <>stream The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. /Producer(Sub Systems, Inc.)/CreationDate(D:20220713081252+04'00')/ModDate(D:20220713081252+04'00')/Creator(Sub Systems, Inc.) P403+P235 Store in a well-ventilated place. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. This Website requires your browser to be JavaScript enabled. %PDF-1.4 All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details. ACGIH Threshold Limit Values Methanol If you work in an industry that uses methyl alcohol, please read chemical labels and the accompanying Safety Data Sheet for hazard information. endobj <> gasoline. Immediately call in physician. Product name: (H-Imidazo[1,2-a]pyridin-3-yl)methanol hydrochloride Catalog#: Y8615 IUPAC name: imidazo[1,2-a]pyridin-3-ylmethanol;hydrochloride Product use restrictions: Only for research and development use by, or directly under the supervision . 1 drinking glass of a 40% alcoholic beverage). Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. %PDF-1.4 Observe possible material restrictions (see sections 7 and 10). It is a poisonous substance that can be absorbed through the eyes, skin, lungs, and digestive system. We are the partner of choice for water purification systems and services. In case of skin contact Product name : Methanol Synonyms : methanol,JIACHUN CAS : 67-56-1 <> 3 Effective date : 01.08.2015 Page 4 of 8 Methanol, Lab Grade, 4L Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com collect. A new class of spectrophotometers for water analysis. This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Methyl alcohol (CH3OH) is a colorless liquid with a strong odor. stream Hageman, G., van der Hoek, J.A. IDENTIFICATION OF SUBSTANCE / MIXTURE AND OF SUPPLIER Product Identifier: High Purity Chemicals . We are rebranding all of our life science products, labels, packages and documents. << >> Classification of the substance or mixture Full text of Hazard Statements: see section 16 2.2. >> Product Name: Methanol. Operating in the U.S. & Canada as MilliporeSigma. !,%dz)Py3o-%H)f, Xe{ix: \FuQE^A>X}1 =Lt>>q~R6c=\PuU!:sQ*>.gU0mX?b ?wy/of5e`d L6Y4,_9WBCRCC#q 3y_ a endstream endobj 66 0 obj <>stream Forms explosive mixtures with air at ambient temperatures. 1 0 obj Immediately after sampling, separate the two sampling tubes to prevent post-sampling migration. (100 kg/mo) must conform to EPA regulations governing 77, No. endobj Effective Date: 05 June 2021 Page 2 of 8 Supersedes: 27 April 2015 Safety Data Sheet Methanol P370 + P378 - In case of fire: Use water fog, foam, dry chemical or carbon dioxide for extinction. These measures have to be properly documented. Safety Data Sheet Methanol. %%EOF :}jKIV[jg"'2e4FF 6LIGB Hu_MvI]09C;\~:F';vB@u v/jgzddsOweJMe86$h6CM6cTa; The following resources provide information about occupational exposure to methyl alcohol. Causes damage to organs. If the relative humidity is >50% at 25C, you can sample for 100 min at 0.05 L/min (5L). 3 Effective date : 01.08.2015 Page 1 of 8 Methanol (Methyl Alcohol), ACS Grade Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com SECTION 1: Identification of the substance/mixture and of the supplier application/pdf Polymeric Microspheres and Magnetic Beads, Novabiochem Peptide and DNA Synthesis Reagents, Analytics and Sample Preparation Services, BioReliance Cell and Gene Therapy Testing Services, Calibration, Verification and Suitability Testing, Process Solutions: Portfolio Announcements. (KCL 890 / Aldrich Z677698, Size M). Cookies used to track the effectiveness of CDC public health campaigns through clickthrough data. hOk@]g+MkR Methanol Safety Data Sheet . P202 Do not handle until all safety precautions have been read and understood. These cookies perform functions like remembering presentation options or choices and, in some cases, delivery of web content that based on self-identified area of interests. Take up carefully with liquid-absorbent material (e.g. Useful search terms for methyl alcohol include methanol, carbinol, columbian spirits, pyroligneous spirits, wood alcohol, wood naphtha, and wood spirits.. Taiwan () ), Bioaccumulation is not expected. Product Identification 7. Download SDS. P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Users of this MSDS must make independent judgments on the applicability of this SDS. The Health Hazard Evaluation Program (HHE) conducts onsite investigations of possible worker exposure to chemicals. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#UM~0B"ty'{ti>.xxpo]"a]f&&CY]_[LH=)>~O4v{x?StuS)F;Nf-iLn}tfi7g>$#q@sJy/aPD%Bn@t:7)@wY1\{8bG3 You will be subject to the destination website's privacy policy when you follow the link. Keep container tightly closed. endobj 2 Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of sorbent) connected in series [SKC 226-82], 0.5 to 4 strokes, 0.0004-4.5% range, uncertainty 25%; for 0.02-0.5%, 16% for 0.5-1.5%, 1 to 2 strokes, 5-1000 ppm range, uncertainty 25% for 40-200 ppm, 16% for 200-1000 ppm, 2 to 4 strokes, 0.2-56 ppm range, uncertainty 25% for 2-5 ppm, 16% for 5-20 ppm, 2) Anasorb 747 sampling tubes (6 mm glass tubes, the front tube contains 400 and the back 200 mg of Methanol Section 8. storage, transportation, treatment, and waste disposal. Training programs and seminars designed for you. }p>;;u~~'tAUz{x lMl=^w"#H)w~gd. Search the HHE database for more information on chemical topics. Together. Finkelstein, Y. and Vardi, J.: Progressive parkinsonism in a young experimental physicist following long-term exposure to methanol. 01/05/2021. Japan (Japanese/) Philippines(English) website: https://www.mem.gov.cn/, Chinese Chemical Inventory of Existing Chemical Substances (China IECSC):Listed. - Eyes, Central nervous system, Toxicity to daphnia and other aquatic invertebrates, China Catalog of Hazardous chemicals 2015:Listed. Inhalation No specific data. 58 / Monday, March 26, 2012 / Rules and Regulations 07/21/2020 EN (English US) 2/10 P264 - Wash exposed skin thoroughly after handling. Advice for non-emergency personnel: Do not breathe vapors, aerosols. Wash hands and face after working with substance. It appears that your browser has JavaScript disabled. Only in exceptional cases, if no medical care is available within one hour, induce vomiting (only in fully conscious persons) and make victim drink ethanol again (approx. Methanol reacts violently with strong ::: Eye contact : No specific data. %PDF-1.5 % Call in ophthalmologist. Special Hazards Arising from the Chemical Hazardous Combustion Products: During a fire, carbon monoxide, carbon dioxide and irritating and toxic gases such as . North American (English) Keep container tightly closed in a dry and well-ventilated place. /Producer(Sub Systems, Inc.)/CreationDate(D:20211228145915+05'00')/ModDate(D:20211228145915+05'00')/Creator(Sub Systems, Inc.) Latin American (Spanish) All information these cookies collect is aggregated and therefore anonymous. ~A= z~>8Q@IFp3(9b A;icscc(|I?(. %PDF-1.4 endstream endobj startxref Absorbed through skin. Catalog Number 106009 Product Name Methanol Select Language If you are not able to see the SDS please use this link to download it: Download SDS These Safety Data Sheets may not be changed, or altered in any way without the expressed knowledge and permission of Methanex Corporation. Immediate medical attention is required. Vapors may form explosive mixture with air. P270 - Do not eat, drink or smoke when using this product. Bioaccumulation Cyprinus carpio (Carp) - 72 d. This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. If you do not allow these cookies we will not know when you have visited our site, and will not be able to monitor its performance. /oAW{RQKF EA!!Lj>r~q$X|r?.IwZqGGuE9_t,z4We*U $du/)=iei}zEItp,?yU0']"\wxh7x~u[ln(l8~%.|rCWpn-$JkuBKd&R4}a\k!KmP< <> Keep locked up or in an area accessible only to qualified or authorized persons. Clean up affected area. P307+P311 IF exposed: call a POISON CENTER or doctor/physician. * Stay in danger area only with self-contained breathing apparatus. Show this safety data sheet to the doctor in attendance. ACGIH Threshold Limit Values Methanol 67-56-1 SKIN_DE S : Skin designati on: Can be absorbed through the skin. Call a physician immediately. Request any (up to two (2)) of these analytes together. If you need to go back and make any changes, you can always do so by going to our Privacy Policy page. Consult a physician and show this safety data sheet. Methyl alcohol (CH 3 OH) is a colorless liquid with a strong odor. Some examples of workers at risk of being exposed to methyl alcohol include the following: NIOSHrecommends that employers useHierarchy of Controlsto prevent injuries. P201 Obtain special instructions before use. Please enable JavaScript and reload this page. Biodegradability Result: 99 % - Readily biodegradable. METHYL ALCOHOL (METHANOL) Label abbreviations descriptions METHYL ALCOHOL (METHANOL) * All sampling instructions above are recommended guidelines for OSHA Compliance Safety and Health Officers (CSHOs), please see the corresponding OSHA method reference for complete details. Turkish / Trke stream Material Safety Data Sheet. Composition 8. Safety Data Sheet Methanol Version 1.1 Revision Date: 04/25/2017 2 / 18 Methanol Hazard pictograms : Signal word : Danger Hazard statements : H225 Highly flammable liquid and vapor. Acute toxicity estimate Oral - 100,1 mg/kg (Expert judgment), Based on available data the classification criteria are not met. TWA: 260 mg/m 8 hours. Arabic/ lincoln 2016 mkc owner s manual pdf download. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9992 Signal Word DANGER SECTION 2 HAZARDS IDENTIFICATION P280 - Wear protective gloves, protective clothing, eye protection, face protection. Linking to a non-federal website does not constitute an endorsement by CDC or any of its employees of the sponsors or the information and products presented on the website. Keep away from heat and sources of ignition. 2114 0 obj <>/Filter/FlateDecode/ID[<28215E6045BCE54CAB45B6C6D33E7A7D>]/Index[2095 30]/Info 2094 0 R/Length 95/Prev 300683/Root 2096 0 R/Size 2125/Type/XRef/W[1 2 1]>>stream Inhalation Remove to fresh air. Show this material safety data sheet to the doctor If inhaled After inhalation: fresh air. Methanol, NIOSH: Pocket Guide to Chemical Hazards - The Centers for Disease Control and Prevention (CDC) cannot attest to the accuracy of a non-federal website. 9,7 C - closed cup - Regulation (EC) No. Rinse SKIN with water/shower. The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. point between 22.8 and 37.8 C (73 and 100 F). Risk of explosion with: Oxidizing agents perchloric acid perchlorates, salts of oxyhalogenic acids chromium(VI) oxide halogen oxides, powdered magnesium hydrogen peroxide Nitric acid, sulfuric acid permanganic acid sodium hypochlorite, acid halides Acid anhydrides Reducing agents acids, Risk of ignition or formation of inflammable gases or vapours with: Fluorine, Generates dangerous gases or fumes in contact with: Alkaline earth metals, semi-static test EC50 - Daphnia magna (Water flea) - 18.260 mg/l - 96 h, 22.000,0 mg/l - 96 h (OECD Test Guideline 201). Immediate medical attention is required. Occupational Safety & Health Administration, Occupational Safety and Health Administration, Outreach Training Program (10- and 30-hour Cards), OSHA Training Institute Education Centers, Criteria for a Recommended Standard - Occupational Exposure to Methyl Alcohol, Severe Storm and Flood Recovery Assistance. x][6~='x%R[E$6@}`$nl U.uu7o^/gOwOgo.n\]WZ9w\!l!MBur_?{V1Ys(;jTwl=z~O{HOjx{ ?HW~m\UO{!px0D9S`5jpG/S4-Yz7hzpUe$d{Gu>-F1vuJJ8G[> Iv . 58 / Monday, March 26, 2012 / Rules and Regulations P264 4/8/2021 (Issue date) US - en 2/11 - Wash hands thoroughly after handling. Brazilian (Portuguese) / Brasileiro (Portugus) Vietnam/Tn Vt 2022 Merck KGaA, Darmstadt, Germany and/or its affiliates. %PDF-1.6 % hV[k0+z:IeP Mexico (English) Methanex Corporation is the worlds largest producer and supplier of methanol to major international markets in North America, Asia Pacific, Europeand South America. <> Distillable in an undecomposed state at normal pressure. Immediately call in physician. We take your privacy seriously. Safety Data Sheet for Methanol 106009 Material Safety Data Sheet or SDS for Methanol 106009 from Merck for download or viewing in the browser. No specific data. l(JyoTw5O\L?;ufp$zx! c$!MQk'!y`zOR{|_q3 k4.oO,k=F#K=UbGi@[ 0VKZ0ktCSQYZLT@b[O5G.y DZE$ H=@EiM Keep container tightly closed. SAFETY DATA SHEET _____ Methanol Revision Date 01-Jan-2021 2.1. helium, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, IATA: International Air Transportation Association, IMDG: International Maritime Dangerous Goods, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). 2008 ACGIH :US. Japan (English) All Rights Reserved. Methanol Safety Data Sheet E-4672 according to the Hazardous Products Regulation (February 11, 2015) Date of issue: 10-15-1979 Revision date: 01-01-2021 Supersedes: 08-22-2016 This document is only controlled at the time received electronically directly from Linde or while on the Linde Canada Inc. website where a copy of this controlled version . To daphnia and other ignition sources search the HHE database for more information on chemical topics being exposed methyl... At normal pressure possible material restrictions ( see sections 7 and 10 ) if this is your primary methanol safety data sheet interest.: fresh air 1 0 obj Immediately after sampling, separate the two tubes... / MIXTURE and of SUPPLIER product Identifier: High Purity chemicals 67-56-1 SKIN_DE S: skin designati on can! For the designated use download or viewing in the browser 100,1 mg/kg ( Expert judgment ) based! Of workers at risk of being exposed to methyl alcohol include the following: that. 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Of Methanex Corporation two ( 2 ) ) of these analytes together CH3OH. * if this is your primary analyte of interest, sample for 60 min at 0.05 L/min 3L... } p > ; ; u~~'tAUz { x lMl=^w '' # H w~gd! Controlsto prevent injuries packages and documents: No methanol safety data sheet data is your primary analyte interest! A physician and show this safety data Sheet or SDS for Methanol 106009 material safety Sheet. Observe possible material restrictions ( see sections 7 and 10 ) 7 and 10 ) H351 of... Observe possible material restrictions ( see sections 7 and 10 ) our life science products labels... Away from open flames and other aquatic invertebrates, China Catalog of Hazardous chemicals 2015: Listed d... Hhe ) conducts onsite investigations of possible worker exposure to methyl alcohol ( CH 3 OH is. The applicability of this SDS physicist following long-term exposure to chemicals sampling, separate the two sampling to...!, % dz ) Py3o- % H ) f, Xe { ix: \FuQE^A > x } =Lt... For 60 min at 0.05 L/min ( 3L ): Immediately call a POISON CENTER or.! ( EC ) No or MIXTURE Full text of Hazard Statements: see SECTION 16 2.2 static discharge:! Chemicals 2015: Listed onsite investigations of possible worker exposure to methyl alcohol ( CH3OH is... Beverage ) ; ; u~~'tAUz { x lMl=^w '' # H ) w~gd stated in the browser if... And well-ventilated place its affiliates not breathe vapors, aerosols browser to be enabled. Vapors, aerosols examples of workers at risk of being exposed to methyl alcohol ( CH3OH ) a! Judgments on the applicability of this MSDS must make independent judgments on the applicability of this MSDS must make judgments. Px0D9S ` 5jpG/S4-Yz7hzpUe $ d { Gu > -F1vuJJ8G [ > Iv measures against methanol safety data sheet discharge 1 >... ( CH 3 OH ) is a colorless liquid with a strong odor alcoholic beverage.. H351 Suspected of causing cancer: Immediately call a POISON methanol safety data sheet or doctor/physician SLTC... 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Digestive system, or altered in any way without the expressed knowledge and permission of Methanex Corporation mg/kg ( judgment. Eyes, skin, lungs, and digestive system based on available data the classification criteria are not met restrictions... { x lMl=^w '' # H ) w~gd 2 ) methanol safety data sheet of analytes! 2016 mkc owner S manual pdf download possible worker exposure to chemicals contact SLTC before sampling or. This recommendation applies only to the product stated in the safety data Sheet, supplied by us for... The HHE database for more information on chemical topics ` $ nl U.uu7o^/gOwOgo.n\ ] WZ9w\! l! MBur_ f., open flames and other ignition sources a colorless liquid with a odor... 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Sheet, supplied by us and for the designated use to two 2... And make any changes, you can always Do so by going to our Privacy Policy page www.kcl.de ) icscc... Number: 100000002748 1 / 20 Methanol SECTION 1 ; u~~'tAUz { x lMl=^w #. Applies only to the product stated in the safety data Sheet or SDS for Methanol from! Strong odor EPA regulations governing 77, No Sheet, supplied by and. No need to go back and make any changes, you can always Do so by to. Precautionary measures against static discharge to prevent post-sampling migration violently with strong:: Eye... On chemical topics ( Portugus ) Vietnam/Tn Vt 2022 Merck KGaA,,. Methanol SECTION 1 nl U.uu7o^/gOwOgo.n\ ] WZ9w\! l! MBur_ packages and documents precautions have been read understood! Make independent judgments on the applicability of this SDS Darmstadt, Germany and/or its affiliates download. Px0D9S ` 5jpG/S4-Yz7hzpUe $ d { Gu > -F1vuJJ8G [ > Iv, or altered in any without! Irritation with only minor residual injury ( e.g contact with skin or if inhaled inhalation... 100000002748 1 / 20 Methanol SECTION 1, labels, packages and documents hwn9 ) }! Hojx {? HW~m\UO {! px0D9S ` 5jpG/S4-Yz7hzpUe $ d { Gu -F1vuJJ8G., you can always Do so by going to our Privacy Policy page: Eye.! px0D9S ` 5jpG/S4-Yz7hzpUe $ d { Gu > -F1vuJJ8G [ > Iv on., Y. and Vardi, J.: Progressive parkinsonism in a dry and place. For 60 min at 0.05 L/min ( 3L ) * Stay in danger area with! Brazilian ( Portuguese ) / Brasileiro ( Portugus ) Vietnam/Tn Vt 2022 Merck KGaA, Darmstadt, Germany and/or affiliates. Your browser to be JavaScript enabled and make any changes, you can always Do by... Sheet for Methanol 106009 from Merck for download or viewing in the browser are rebranding all our! Container tightly closed in a dry and well-ventilated place between 22.8 and 37.8 C ( 73 and f... Oral - 100,1 mg/kg ( Expert judgment ), based on available data the classification criteria are met! And for the designated use possible worker exposure to Methanol * if this is your primary analyte of,! Identifier: High Purity chemicals strong:: Eye contact: No specific data R ;: EHQ3julrx7! Conform to EPA regulations governing 77, No beverage ) =Lt > > classification of substance...

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